File:Artemisinin synthesis.svg
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Size of this PNG preview of this SVG file: 434 × 599 pixels. Other resolutions: 174 × 240 pixels | 347 × 480 pixels | 556 × 768 pixels | 741 × 1,024 pixels | 1,483 × 2,048 pixels | 724 × 1,000 pixels.
Original file (SVG file, nominally 724 × 1,000 pixels, file size: 99 KB)
Summary
| Description |
English: Biosynthesis of Artemisinin |
| Date | |
| Source | Own work |
| Author | Krishnavedala |
| SVG development |  This vector image was created with an unknown SVG tool. |
LaTeX source code
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|---|
\documentclass[12pt,border=1pt,crop,multi=false,tikz,class=scrartcl]{standalone}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage{chemfig,chemmacros,chemformula}
\usepackage{lmodern}
\usetikzlibrary{decorations.pathmorphing}
\chemsetup[chemformula]{font-shape=sf,format=\sffamily}
\chemsetup[option]{circletype=math}
\renewcommand*{\familydefault}{\sfdefault}
\renewcommand*\printatom[1]{\ensuremath{\mathsf{#1}}}
\setatomsep{1.8em}
\setdoublesep{.6ex}
\setarrowdefault{,.8,semithick}
\setbondstyle{thick}
\makeatother
\begin{document}
\definesubmol\nobond{-[,0.2,,,draw=none]}
\schemestart
\chemfig{PPO-[::30]-[2]=^[::60](-[::60])-[2]-[::-60]-[::-60]=^[::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{@{d21}\fmch OPP-[::30,.2,,,draw=none]-[2,,,,draw=none](-[@{d24}::-60](!\nobond\fpch))=_[@{d23}::60]@{d22}(-[::60])-[2]-[::-60]-[::-60]=^[::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{@{d32}OPP-[@{d31}2,1.2,1](-[:-150])(-[@{d34}:-30]=^[@{d33}::60]@{d36})-[2]-[::-60]-[::-60]=^[@{d35}::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)(<[@{d41}:20]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60]@{d42}(!\nobond\fpch)(-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow[-110]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60]@{d52}(<:[6]H)(!\nobond\fpch)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60]=_[@{d51}6](-[::60])-[::-60]}
\arrow[180]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](-[6,.4,,,draw=none]\fpch)(-[@{d62}::60]-[@{d61}::60]H)-[::-60]}
\arrow[180]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]}
\arrow[-90]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]-[::-60]HO}
\arrow[,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]=_[::-60]O}
\arrow[,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60](-[6]OH)=[::-60]O}
\arrow(@c8--)[-90,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](<[::60])-[::-60]-[::-65]HO}
\arrow(@c9--)[-90,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](<[::60])-[::-60]=_[::-60]O}
\arrow(@c10--)[-90,.6,dashed]
\chemfig{@{d132}O=[@{d131}]@{d134}O-[::30,.7,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[@{d133}::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60](-[6]OH)=[::-60]O}
\arrow[-55,.7]
\chemfig{*6((-[4])(<:[:-135]O-[::60]OH)--(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))(<:[6]H)-(<:[2]H)---) }
\arrow[180]
\subscheme{
\chemfig{H_2O}
\arrow[-30,.1,draw=none]
\chemfig{*6((-[@{d172}4])(<:[:-135]@{d174}O-[@{d175}::60]@{d176}OH)-[@{d173}]-(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))----) }
}
\arrow[180]
\chemfig{[:-25.71]*7((-[::-120])(-OH)-O-=(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\arrow[180]
\chemfig{-[:30](=[::60]O)-[::-60]-[::60]-[::-60](*6(-(-=^[::60]O)-(<(<[::60])-[::-60]HO_2C)---(<:[2])(<[:20]H)-))<:[2]H}
\arrow{->[*0{\ch{O2}}]}[-90]
\chemfig{-[:30]@{d202}(=[::60]O)-[::-60]-[::60]-[::-60](*6(-(-[:150]H|@{d201}O|O)(-=^[::60]O)-(<(<[::60])-[::-60]HO_2C)---(<:[2])(<[:20]H)-))<:[2]H}
\arrow[,1]
\chemfig{[:-25.71]*7((-[::-120]H|@{d211}O)(-)(<:[:20]O?)-[,,,,draw=none]-[,,,,draw=none]@{d212}(=^[@{d213}6]O)-(<:[180]O?)(*6(-(<(<[::60])-[::-60]HO_2|@{d214}C)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\arrow[,1]
\chemfig{[:-25.71]*7((<)(<:[:20]O?[a])-O-(<:[6]O?[b])-(<:[180]O?[a])(*6(-(<(<[::60])-[::-60]?[b]=[::60]O)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\chemmove[-stealth, shorten >=2pt, shorten <=2pt]{
\draw (d21) .. controls +(north west:12mm) and +(north west:5mm) .. (d22);
\draw (d23) .. controls +(north:5mm) and +(north:5mm) .. (d24);
\draw (d31) .. controls +(west:5mm) and +(north west:5mm) .. (d32);
\draw (d33) .. controls +(north:5mm) and +(north:5mm) .. (d34);
\draw (d35) .. controls +(south:5mm) and +(north east:5mm) .. (d36);
\draw (d41) .. controls +(north:5mm) and +(south:5mm) .. (d42);
\draw (d51) .. controls +(west:5mm) and +(south east:5mm) .. (d52);
\draw (d61) .. controls +(north:5mm) and +(north east:5mm) .. (d62);
\draw (d131) .. controls +(north:5mm) and +(north:5mm) .. (d132);
\draw (d133) .. controls +(south west:5mm) and +(north:5mm) .. (d134);
\draw (c16) .. controls +(north east:15mm) and +(north:5mm) .. (d172);
\draw (d173) .. controls +(south:5mm) and +(east:5mm) .. (d174);
\draw (d175) .. controls +(west:5mm) and +(west:5mm) .. (d176);
\draw (d201) .. controls +(south:5mm) and +(south:5mm) .. (d202);
\draw (d211) .. controls +(south:5mm) and +(west:5mm) .. (d212);
\draw (d213) .. controls +(east:5mm) and +(north:5mm) .. (d214);
}
\schemestop
\end{document}
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Licensing
Krishnavedala, the copyright holder of this work, hereby publishes it under the following license:
This file is licensed under the Creative Commons Attribution-Share Alike 4.0 International license.
Attribution:
- You are free:
- to share – to copy, distribute and transmit the work
- to remix – to adapt the work
- Under the following conditions:
- attribution – You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- share alike – If you remix, transform, or build upon the material, you must distribute your contributions under the same or compatible license as the original.
File history
Click on a date/time to view the file as it appeared at that time.
| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 15:34, 11 April 2015 | | 724 × 1,000 (99 KB) | wikimediacommons>Krishnavedala | optimized regenering using dvisvgm |
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